IB Physics Notes For Thermal Physics
Temperature And Heat Flow
The direction of the natural flow of thermal energy between two objects is determined by the 'hotness' of each object.
Thermal energy naturally flows from hot to cold. The temperature of an object is a measure of how hot it is. In other words, if two objects are placed in thermal contact, then the temperature difference between the two objects will determine the direction of the natural transfer of thermal energy. Thermal energy is naturally transferred 'down' the temperature difference - from high temperature to low temperature.
Eventually, the two objects would be expected to reach the same temperature. When this happens, they are said to be in thermal equilibrium.
Heat is not a substance that flows from one object to another. What has happened is that thermal energy has been transferred. Thermal energy (heat) refers to the non-mechanical transfer of energy between a system and its surroundings.
Kelvin And Celsius
In order to use Kelvin and Celsius, you do not need to understand the details of how either of these scales has been defined, but you do need to know the relation between them. Most everyday thermometers are marked with the celsius scale and temperature Is quoted in degrees Celsius (°C).
There is an easy relationship between a temperature 'Tas' measured on the Kelvin scale and the corresponding temperature 't' as measured on the Celsius scale. The approximate relationship is T (K) = (°C) + 273. This means that the 'size' of the units used on each scale is identical, but they have different zero points.
The Kelvin scale is an absolute thermodynamic temperature scale and a measurement on this scale is also called the absolute temperature. Zero Kelvin is called absolute zero.
For a given sample of gas, the pressure, the volume and the temperature are all related to one another.
The SI units of pressure are or Pa (Pascals). 1*Pa = 1*N
The temperature, t, of the gas is measured in °C or K
In order to investigate how these quantities are interrelated, we choose:
one quantity to be the independent variable (the thing we alter and measure)
another quantity to be the dependent variable (the second thing we measure).
The third quantity needs to be controlled (i.e. kept constant ).
The specific values that will be recorded also depend on the mass of gas being investigated and the type of gas being used so these need to be controlled as well.
Internal Energy Of Molecules
- The molecules have kinetic energy. They are moving. To be absolutely precise. a molecule has either translational kinetic energy
- The molecule also has potential energy because of the intermolecular forces.
- Molecules with large mass move with a lower average speed
- Molecules with a small mass, move with a higher average speed
Specific Heat Capacity
- Two different blocks with the same mass and same energy input will have a different temperature change. We define the thermal capacity C of an object as the energy required to raise its temperature by 1 K.
- Different objects (even different samples of the same substance) will have different values of heat capacity.
- Specific heat capacity is the energy required to raise a unit mass of a substance by 1 K. 'Specific' here just means 'per unit mass'.
- A particular gas can have many different values of specific heat capacity—it depends on the conditions.
- It generally takes the same amount of energy to raise the temperature of an object from 25 °C to 35 °C as it does for the same object to go from 402 °C to 412 °C. This is only true so long as energy is not lost from the object.
- If an object is raised above room temperature, it starts to lose energy. The hotter it becomes, the greater the rate at which it loses energy.
Methods Of Measuring Heat Capacities And Specific Heat Capacities
- In this method, the following are the sources of experimental error come from the loss of thermal energy from the apparatus.
- The container for the substance and the heater will also be warmed up.
- It will take some time for the energy to be shared uniformly through the substance.
Method of Mixtures
- The known specific heat capacity of one substance can be used to find the specific heat capacity of another substance.
- Measure the masses of the liquids
- Measure the two starting temperatures
- Mix the two liquids together.
- Record the maximum temperature of the mixture
- If no energy is lost from the system then, energy lost by hot substance cooling down = energy gained by cold substance heating up
- The main source of experimental error is
- The loss of thermal energy from the apparatus; particularly while the liquids are being transferred.
- The changes in the temperature of the container also need to be taken into consideration for a more accurate result.
The States Of Matter And Latent Heat
When a substance changes phase, the temperature remains constant even though thermal energy is still being transferred.
Cooling Curve For Molten Lead (Idealized)
The amount of energy associated with the phase change is called the latent heat. The technical term for the change of phase from solid to liquid is fusion and the term for the change from liquid to gas is vaporization.
The energy given to the molecules does not increase their kinetic energy so it must be increasing their potential energy. Intermolecular bonds are being broken and this takes energy. When the substance freezes bonds are created and this process releases energy.
It is a very common mistake to think that the molecules must speed up during a phase change. The molecules in water vapour at 100 °C must be moving with the same average speed as the molecules in liquid water at 100 °C.
The specific latent heat of a substance is defined as the amount of energy per unit mass absorbed or released during a change of phase. In symbols,
Specific latent heat
In the idealized situation of no energy loss, a constant rate of energy transfer into a solid substance would result in a constant rate of increase in temperature until the melting point is reached:
The specific heat capacity of the solid as the gradient of the line that corresponds to the liquid phase is greater than the gradient of the line that corresponds to the solid phase. A given amount of energy will cause a greater increase in temperature for the liquid when compared with the solid.
Methods Of Measuring Latent Heats
- Although pressure and volume both vary linearly with Celsius temperature, neither pressure nor volume is proportional to Celsius temperature.
- A different sample of gas would produce a different straight-line variation for pressure (or volume) against temperature but both graphs would extrapolate back to the same low temperature, -273 °C. This temperature is known as absolute zero.
- As pressure increases, the volume decreases. In fact, they are inversely proportional.
- At constant constant (the pressure law)
- At constant constant (Charles's law)
- At constant constant (Boyle's law)
- These relationships are known as Ideal gas laws.
- The temperature is always expressed in Kelvin
- . These laws do not always apply to experiments done with real gases.
- A real gas is said to 'deviate' from ideal behaviour under certain conditions (e.g. high pressure).
The three ideal gas laws can be combined together to produce one mathematical relationship: constant
This constant will depend on the mass and type of gas.
If we compare the value of this constant for different masses of different gases, it turns out to depend on the number of molecules that are in the gas - not their type.
In this case, we use the definition of the mole to state that for n moles of an ideal gas: a universal constant
The universal constant is called the molar gas constant R. The SI unit for R is J
R = 8.314 J
The concepts of the mole, molar mass and the Avogadro constant are all introduced so as to be able to relate the mass of gas (an easily measurable quantity) to the number of molecules that are present in the gas.
- Ideal gas
- An ideal gas Is one that follows them, laws for all values of P, Vand T
Avogadro constant, NA
Ideal Gases And Real Gases
An ideal gas is a one that follows the gas laws for all values of p, V and T and thus ideal gases cannot be liquefied. Real gases, however, can approximate to ideal behaviour providing that the intermolecular forces are small enough to be ignored. For this to apply, the pressure/density of the gas must be low and the temperature must be moderate.
Molecular Model Of An Ideal Gas
- Kinetic Model Of An Ideal Gas
- Newton's laws apply to molecular behaviour
- There are no intermolecular forces except dining a collision
- The molecules are treated as points
- The molecules are in random motion
- The collisions between the molecules arc elastic (no energy is lost)
- There is no time spent in these collisions.
- The pressure of a gas is a result of collisions between the molecules and the walls of the container in which that gas has been stored.
- When a molecule bounces off the walls of a container its momentum changes (due to the change in direction - momentum is a vector).
- There must have been a force on the molecule from the wall (Newton II).
- There must have been an equal and opposite force on the wall from the molecule (Newton III).
- Each time there is a collision between a molecule and the wall, a force is exerted on the wall.
- The average of all the microscopic forces on the wall over a period of time means that there is effectively a constant force on the wall from the gas.
- This force per unit area of the wall is what we call pressure. .
- Since the temperature of a gas is a measure of the average kinetic energy of the molecules, as we lower the temperature of a gas the molecules will move slower.
- At absolute zero, we imagine the molecules to have zero kinetic energy. We cannot go any lower because we cannot reduce their kinetic energy any further!
- Macroscopically, at a constant volume, the pressure of a gas is proportional to its temperature in kelvin.
- Microscopically this can be analysed as follows
- If the temperature of gas goes up, the molecules have more average kinetic energy - they are moving faster on average.
- Fast-moving molecules will have a greater chance of momentum when they hit the walls of the container. Thus the microscopic force from each molecule will be greater.
- The molecules are moving faster so they hit the walls more often.
- For both these reasons, the total force on the wall goes up.
- Thus the pressure goes up. low-temperature high temperature
Macroscopically, at constant pressure, the volume of a gas is proportional to its temperature in kelvin.
Microscopically this can be analysed as follows
A higher temperature means faster moving molecules.
Faster moving molecules hit the walls with a greater microscopic force
If the volume of the gas increases, then the rate at which these collisions take place on a unit area of the wall must go down.
The average force on a unit area of the wall can thus be the same. Thus the pressure remains the same.
- Macroscopically, at a constant temperature, the pressure of a gas is inversely proportional to its volume.
- Microscopically this can be seen to be correct.
- The constant temperature of gas means that the molecules have a constant average speed.
- The microscopic force that each molecule exerts on the wall will remain constant.
- Increasing the volume of the container decreases the rate with which the molecules hit the wall -the average total force decreases.
- If the average total force decreases the pressure decreases.
- When the volume of a gas is isothermally compressed to a smaller volume, the pressure exerted by the gas on the container walls increases. The best microscopic explanation for this pressure increase is that at the smaller volume
- A. the individual gas molecules are compressed
- B. the gas molecules repel each other more strongly
- C. the average velocity of gas molecules hitting the wall is greater
- D. the frequency of collisions with gas molecules with the walls is greater
- A lead bullet is fired into an iron plate, where it deforms and stops. M a result, the temperature of the lead increases by an amount AT. For an identical bullet hitting the plate with twice the speed, what is the best estimate of the temperature increase?
- In winter, in some countries, the water in a swimming pool needs to be heated.
- Estimate the cost of heating the water in a typical swimming pool from 5 °C to a suitable temperature for swimming. You may choose to consider any reasonable size of the pool. Clearly show any estimated values. The following information will be useful:
- Specific heat capacity of water 4186 J
- The density of water 1000 kg
- Cost per kW h of electrical energy $0.10
- (i) Estimated values
- (ii) Calculations
- This question is about determining the specific latent heat of fusion of ice. A student determines the specific latent heat of fusion of ice at home. She takes some ice from the freezer, measures its mass and mixes it with a known mass of water in an insulating jug. She stirs until all the ice has melted and measures the final temperature of the mixture. She also measured the temperature in the freezer and the initial temperature of the water. She records her measurements as follows:
- Mass of ice used: = 0.12 kg
- The initial temperature of ice: Ti —12 °C
- The initial mass of water: = 0.40 kg
- The initial temperature of water: = 22 °C
- The final temperature of the mixture: = 15 °C
- The specific heat capacities of water and ice are
- = 4.2 kJ ° and = 2.1 kJ °
- a) Set up the appropriate equation, representing energy transfers during the process of coming to thermal equilibrium, that will enable her to solve for the specific latent heat Li of ice. Insert values into the equation from the data above, but do not solve the equation.
- b) Explain the physical meaning of each energy transfer term in your equation (but not each symbol).
- State an assumption you have made about the experiment, in setting up your equation in (a).
- d) Why should she take the temperature of the mixture immediately after all the ice has melted?
- e) Explain from the microscopic point of view, in terms of molecular behaviour, why the temperature of the ice does not increase while it is melting.