Chemistry HL
Chemistry HL
6
Chapters
243
Notes
Chapter 1 - Models Of The Particulate Nature Of Matter
Chapter 1 - Models Of The Particulate Nature Of Matter
Chapter 2 - Models Of Bonding & Structure
Chapter 2 - Models Of Bonding & Structure
Chapter 3 - Classification Of Matter
Chapter 3 - Classification Of Matter
Chapter 4 - What Drives Chemical Reactions?
Chapter 4 - What Drives Chemical Reactions?
Chapter 5 - How Much, How Fast & How Far?
Chapter 5 - How Much, How Fast & How Far?
Chapter 6 - What Are The Mechanisms Of Chemical Change?
Chapter 6 - What Are The Mechanisms Of Chemical Change?
IB Resources
Chapter 4 - What Drives Chemical Reactions?
Chemistry HL
Chemistry HL

Chapter 4 - What Drives Chemical Reactions?

Determining Reaction Spontaneity Using Gibbs Energy

Word Count Emoji
360 words
Reading Time Emoji
2 mins read
Updated at Emoji
Last edited on 5th Nov 2024

Table of content

Key Concept - Gibbs Energy 🌟

  • Gibbs Energy (∆G⦵) is like a crystal ball that tells us if a reaction will go ahead or take a nap under standard conditions.
  • Formula time: ∆G⦵ = ∆H⦵ − T∆S⦵
    • ∆H⦵ = Change in enthalpy (heat content)
    • ∆S⦵ = Change in entropy (measure of disorder)
    • T = Absolute Temperature in Kelvin (K)

👉 Use the data booklet for the values of ∆H⦵ and ∆S⦵.

 

🍦 Real-world example: Imagine you want to buy an ice cream. Your decision (whether to buy or not) depends on two things: how much money you have (enthalpy) and how badly you want that sweet treat (entropy). The weather (temperature) then plays its role; on a hot day, you might be more desperate for ice cream (spontaneous)!

Hot & Cold Reactions - Endothermic & Entropy! 🔥

  • Endothermic Reactions

    • Absorb heat (feels cold)
    • ∆H⦵ is positive
  • Positive Entropy Change

    • More disorder (like a messy bedroom)
    • ∆S⦵ is positive

Temperature's Role in the Dance: 🌡️

When both ∆H⦵ and ∆S⦵ are positive

  • High Temperature: The entropy effect dominates. ΔG⦵ becomes negative, so the reaction says, "Let's party!" (spontaneous).
  • Low Temperature: The enthalpy effect takes over. ΔG⦵ turns positive, so the reaction goes "Nah, maybe later!" (non-spontaneous).

🎈Fun Fact: The exact temperature where the reaction switches from a “maybe later” to “let’s party” is when ΔG⦵ = 0! Using the equation:

0 = ∆H⦵ − T∆S⦵

When you rearrange it for T:

T = ∆H⦵/∆S⦵

This equation lets you be the genius who figures out the temperature where a reaction becomes spontaneous! 🌟

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IB Resources
Chapter 4 - What Drives Chemical Reactions?
Chemistry HL
Chemistry HL

Chapter 4 - What Drives Chemical Reactions?

Determining Reaction Spontaneity Using Gibbs Energy

Word Count Emoji
360 words
Reading Time Emoji
2 mins read
Updated at Emoji
Last edited on 5th Nov 2024

Table of content

Key Concept - Gibbs Energy 🌟

  • Gibbs Energy (∆G⦵) is like a crystal ball that tells us if a reaction will go ahead or take a nap under standard conditions.
  • Formula time: ∆G⦵ = ∆H⦵ − T∆S⦵
    • ∆H⦵ = Change in enthalpy (heat content)
    • ∆S⦵ = Change in entropy (measure of disorder)
    • T = Absolute Temperature in Kelvin (K)

👉 Use the data booklet for the values of ∆H⦵ and ∆S⦵.

 

🍦 Real-world example: Imagine you want to buy an ice cream. Your decision (whether to buy or not) depends on two things: how much money you have (enthalpy) and how badly you want that sweet treat (entropy). The weather (temperature) then plays its role; on a hot day, you might be more desperate for ice cream (spontaneous)!

Hot & Cold Reactions - Endothermic & Entropy! 🔥

  • Endothermic Reactions

    • Absorb heat (feels cold)
    • ∆H⦵ is positive
  • Positive Entropy Change

    • More disorder (like a messy bedroom)
    • ∆S⦵ is positive

Temperature's Role in the Dance: 🌡️

When both ∆H⦵ and ∆S⦵ are positive

  • High Temperature: The entropy effect dominates. ΔG⦵ becomes negative, so the reaction says, "Let's party!" (spontaneous).
  • Low Temperature: The enthalpy effect takes over. ΔG⦵ turns positive, so the reaction goes "Nah, maybe later!" (non-spontaneous).

🎈Fun Fact: The exact temperature where the reaction switches from a “maybe later” to “let’s party” is when ΔG⦵ = 0! Using the equation:

0 = ∆H⦵ − T∆S⦵

When you rearrange it for T:

T = ∆H⦵/∆S⦵

This equation lets you be the genius who figures out the temperature where a reaction becomes spontaneous! 🌟

Unlock the Full Content! File Is Locked Emoji

Dive deeper and gain exclusive access to premium files of Chemistry HL. Subscribe now and get closer to that 45 🌟

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